This study explores how doctoral graduates weigh considerations of employment sectors and cities in their career decision-making processes. Guided by Social Cognitive Career Theory and a Four-quadrant Model, researchers analysed interviews from 40 STEM doctoral graduates in China. Findings demonstrate that self-efficacy, outcome expectations and goal-setting were factors in participants' interests and selections of academic careers. Three types of doctoral graduates were identified: (1) highfliers, (2) academic loyalists and (3) city pickers. While participants prioritize employment sectors and cities differently, cities played a significant role in their career choices which intersected with gender and class factors. Female doctoral graduates were more inclined to follow their partners, while those from socioeconomically disadvantaged backgrounds tended to prioritize cost of living factors at the expense of pursuing opportunities in top-tier cities. Implications suggest that factors undergirding doctoral graduates' career choices rely on the interaction between geographical locations and employment sector opportunities.