In multielectron atoms or molecules, quantized electronic energy states known as term states provide a framework for interpreting absorption and emission spectra. Enumerating the term states associated with any particular electron configuration is possible using time-honored procedures, but the underpinnings of the methods do not always receive…

Students collect magnetic susceptibility data to verify that Hund's rule correctly predicts electronic configurations. Systems examined include three commercially available lanthanide(III)-containing complexes of the form M(acac)[subscript 3](H[subscript 2]O)[subscript 2] (where M = La(III), Nd(III), and Gd(III), and acac denotes the [CH[subscript…