Starting with the fundamental and general criterion for a spontaneous process in thermodynamics, delta S[subscript tot] greater than or equal to 0, we review its relationships to other criteria, such as delta A and delta G, that have limitations. The details of these limitations, which can be easily overlooked, are carefully explicated. We also…

Nearly 50 years ago, Henry Bent published his groundbreaking article in this "Journal" introducing the "global" formulation of thermodynamics. In the following years, the global formulation was elaborated by Bent and by one of the present authors. The global formulation of the first law focuses on conservation of energy and the recognition that…

Different formulations of thermodynamic work "w" as a pressure-volume integral are examined for a piston moving against a gas in an irreversible process. Proper expressions are obtained using the instantaneous pressure of the gas on the piston as the integrand and also using certain external pressures as the integrand. There are two common yet…