This "Science note" teaching lesson explores the possible reaction between the ions in a reaction mixture consisting of iron(II) iodide and potassium dichromate(VI) in acidified aqueous solution. The electrode potentials will be used to deduce any spontaneous reactions under standard thermodynamic conditions (298 K, 1 bar (approximately…

This edited volume presents innovative current research in the field of Science Education. The chapter's deal with a wide variety of topics and research approaches, conducted in a range of contexts and settings. Together they make a strong contribution to knowledge on science teaching and learning. The book consists of selected presentations from…

This paper presents a formulation of the second law of thermodynamics couched in terms of Shannon's measure of information. This formulation has an advantage over other formulations of the second law. First, it shows explicitly what is the thing that changes in a spontaneous process in an isolated system, which is traditionally referred to as the…

Offers suggestions for introducing polymer topics into: (1) introductory chemical engineering; (2) transport phenomena and unit operations; (3) chemical engineering thermodynamics; and (4) reaction engineering. Also included for each area are examples of textbooks in current use and a few typical problems. (JN)

Describes an exercise in which the entropy maximum is illustrated with a chemical example. The exercise allows students to work with an isolated, chemically reactive system and shows that the entropy of a nonisolated system can pass through a maximum but does so at a nonequilibrium point. (JN)

Heat is defined as a random or nondirected internal energy transfer between different bodies at different temperatures. Work is defined as oriented or nonrandom internal energy transfer. Both heat and work are demonstrated to lead to increases in temperature via interpretations from gas kinetic theory. (JN)

Discusses misconceptions (in several thermodynamics statements) that seem to be particularly common among students who have finished a one-semester, junior-level course in chemical thermodynamics. When presented as true/false questions, these statements are usually judged true, although each requires at least one more condition to be satisfied.…

The concept of an ideal solution is ordinarily introduced in freshman chemistry by means of Raoult's Law, which states that the vapor pressure of a volatile component of a solution is proportional to its mole fraction. The relationship of this law to molecular size is discussed. (JN)

Provides a question (with the acceptable answer) designed to test students' ability to apply, and extend, the concept of thermodynamic work discussed in the classroom. The question was originally designed as a part of a take-home examination. (JN)

One of the most useful methods of understanding chemical equilibria is provided by Le Chatelier's principle. The relationships between this principle, temperature, and entropy are discussed. Tables with thermodynamic data for some net reactions commonly used to illustrate the principle and for reactions involving gases are included. (JN)

Shows how to present thermodynamic concepts for reactions taking place in the "dry wall" (solids and gases), allowing chemists to study the making and breaking of bonds and the change in polar character of bonds. (JN)

Describes an interactive, screen-oriented, BASIC computer program for an IBM PC microcomputer with graphics capability. The program (which uses about 34K RAM and utilizes a menu format) represents a general method for calculating thermodynamic properties of chemical reactions from thermal data for reactants and products. (JN)

Describes an experiment in which the final speed of a toy car is predicted by measuring the elastic potential energy stored in its spring at the start and the energy lost to friction during the run. Conservation of energy is discussed and the necessary mathematical formulas are presented. (BC)

Problems of equilibria in condensed phases (particularly those involving solutes in dilute solutions) are encountered by students in their laboratory work; the thermodynamics of these equilibria is neglected in many textbooks. Therefore, several aspects of this topic are explored, focusing on pressure dependence and choice of standard state. (JN)

Reviews "Thermodynamics" (Cross Educational Software) and "Calorimetry and Thermodynamics" (Educational Materials and Equipment Company). The first package has seven programs (briefly described) while the second package contains virtually an identical subset of the Cross package. (JN)