Outlines a laboratory exercise that makes use of Beer's Law plots of cysteine constructed at several pH values over a broad range of wavelengths to estimate the tautomeric ratio (R) of two singly charged ionic forms, calculate the microscopic constants, and construct ultraviolet spectra for both light absorbing species. (CW)

Examines the usefulness of cyclic voltammetry to the determination of a complex compound's stoichiometry. Discusses the experimental design, laboratory equipment, and results. (CW)

Describes experiments in which students prepare in situ soluble complexes of metal ions with different ligands and observe and estimate the change in formal potential that the ion undergoes upon complexation. Discusses student formation and analysis of soluble complexes of two different metal ions with the same ligand. (CW)

Investigates the effects of using scientific apparatus versus household objects on the accuracy of primary school children in a simple titration exercise. Indicates no significant difference between the accuracy obtained using the two types of apparatus at the beginning, but improved performance for children using scientific apparatus by the end.…

Discusses general construction principles for miniaturized laboratory glassware. Describes a prototype experimental kit that allows the carrying out of all standard laboratory operations and discusses a trial use of the equipment with students 16- to 17-years-old. (CW)

Describes an experiment to be performed in an undergraduate biochemistry laboratory that is based on a gradient centrifugation system employing a simple bench top centrifuge, a freezer, and frozen surcose gradient solution to separate macromolecules and subcellular components. (CW)

Describes a kinetic and mechanistic investigation of ascorbic acid by a substitution-inert complex in acidic medium suitable for the undergraduate level. Discusses obtaining the second order rate constant for the rate determining step at a given temperature and comparison with the value predicted on the basis of the Marcus cross-relation. (CW)

Discussed are the potential hazards associated with nitric acid, inorganic and organic nitrate salts, alkyl nitrates, acyl nitrates, aliphatic nitro compounds, aromatic nitro compounds, and nitration reactions. (CW)

Describes a simplified redox method for total iron analysis suitable for execution in a three-hour laboratory period by general chemistry students. Discusses materials, procedures, analyses, and student performance. (CW)

Presented are four experiments for use in two wet analysis courses. These include comparisons and enzyme analysis. In each case, the theory behind each experiment is discussed. (CW)

Discussed are selected application and future trends in supercritical fluid chromatography (SFC). The greatest application for SFC involves those analytes that are difficult to separate using GC or LC methods. Optimum conditions for SFC are examined. Provided are several example chromatograms. (MVL)

Describes an experiment in which students are given a naturally occurring oligosaccharide as an unknown and are asked to determine both its monosaccharide composition and its structure. Discusses methods and experimental techniques including thin layer chromatography and the use of enzymes. (CW)

Research indicates that the educational effectiveness of Microcomputer-Based Laboratories (MBL) may be due to the real time nature of the experience. This article describes a study where kinesthetic feedback was completely removed by giving students only visual replications of a motion situation. If simultaneity of perception is the important…

The target of difficulty of the Educational Technology Center (ETC) Heat and Temperature Group is basic thermal physics, particularly the differentiation between heat and temperature. High school teachers often find that thermal concepts are very difficult for their students to master and attribute students' difficulties at least in part to the…