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Barrow, Gordon M. – Journal of Chemical Education, 1988
Draws a distinction between the terms "heat and work" and "energy" in terms of the teaching of thermodynamics. Gives examples using enthalpy and constant pressure processes, free energy and spontaneity, and free energy and available mechanical energy. Concludes that there is no thermodynamic role for the terms "heat"…
Descriptors: College Science, Energy, Heat, Higher Education
Peer reviewed Peer reviewed
Bratsch, Steven G. – Journal of Chemical Education, 1988
Discusses a revised and extended version of the Mulliken electronegativities. Describes applications and limitations implied by this version. (CW)
Descriptors: Atomic Structure, Atomic Theory, Chemistry, College Science
Peer reviewed Peer reviewed
Bratsch, Steven G. – Journal of Chemical Education, 1988
Discusses a revision and extension of the Mulliken electronegativity scale to consider 50 elements. Describes the calculation of valence-state promotion energies and Mulliken atomic electronegativities and the conversion of Mulliken electronegativities to Pauling units. (CW)
Descriptors: Atomic Structure, Atomic Theory, Chemistry, College Science
Peer reviewed Peer reviewed
Agmon, Noam – Journal of Chemical Education, 1988
Presents a quantitative treatment of ionization potentials of isoelectronic atoms. By looking at the single-electron view of calculating the total energy of an atom, trends in the screening and effective quantum number parameters are examined. Approaches the question of determining electron affinities. (CW)
Descriptors: Atomic Structure, Atomic Theory, Chemistry, College Science
Peer reviewed Peer reviewed
Woolf, A. A. – Journal of Chemical Education, 1988
Reviews a method for determining oxidation numbers in covalent compounds and balancing mixed organic-inorganic or purely organic systems. Points out ambiguities presented when adjacent atoms have small or zero electronegativity differences. Presents other limitations that arise when using electronegativity values. (CW)
Descriptors: Atomic Structure, Atomic Theory, Chemical Bonding, Chemical Reactions