Kinetic versus thermodynamic control of product formation is discussed in undergraduate textbooks, and journal papers suggest suitable experiments to illustrate this concept. In rationalizing experimental observations, this paper offers a new alternative to that conventionally employed and provides students with an interesting exercise in…

Describes an interactive graphics package which illustrates the phase behavior of binary mixtures. The package has been successfully used with graduate and undergraduate students in the chemical engineering curriculum at Cornell University. Features contributing to this success are noted. (JN)

The method of Clarke and Glew is broadly applicable to studies of the temperature dependence of equilibrium constant measurements. The method is described and examples of its use in comparing calorimetric results and temperature dependent gas solubility studies are provided. (JN)

A diffusional driving force, called the radial force, which is responsible for the increase with time of the scalar separation between a fixed point and a particle undergoing three-dimensional Brownian motion, is derived using Boltzmann's equation. (Author/HM)

Describes the uses of finite element methods in solving problems of heat transfer, fluid flow, etc. Suggests that engineers should know the general concepts and be able to apply the principles of finite element methods. (Author/WB)

Describes experiments designed to investigate the cooling rate of microwave-boiled water as compared to that of stove-boiled water. Concludes that within experimental limits, microwave-boiled water and stove-boiled water cool at the same rate. (JRH)

Describes a paradox in the equation for thermal expansion. If the calculations for heating a rod and subsequently cooling a rod are determined, the new length of the cool rod is shorter than expected. (PR)

Presents notes on three physics experiments on (1) light and lenses, (2) determination of the pVT surface of a freon, and (3) use of an eyepiece with microscopes and telescopes. (RH)

Photographs illustrate several principles of physics which can be observed in everyday situations. (CP)

Presents a study designed to evaluate the influence of temperature on the equilibrium and the structural changes of the complexes interpreted in terms of ligand field theory. (CW)

Draws a distinction between the terms "heat and work" and "energy" in terms of the teaching of thermodynamics. Gives examples using enthalpy and constant pressure processes, free energy and spontaneity, and free energy and available mechanical energy. Concludes that there is no thermodynamic role for the terms "heat"…

Describes three examination questions which could be used in college chemistry courses. Discusses each problem and gives acceptable solutions. Problems include: "A Multi-Topic Problem for General Chemistry"; "Consumption of Air by Biuret Reagent--a Question Involving Experimental Design"; and "An Instructive Problem in Heterogeneous Equilibrium."…

Demonstrates, with a set of definitive examples, how polymer principles can be introduced into the first undergraduate physical chemistry course in a very natural way. The intent is to encourage introduction of polymer-related material into conventional physical chemistry courses without sacrificing any rigor associated with such courses. (JN)

Indicates that teaching of mass transfer can be improved by: (1) using a single, simple definition of mass transfer coefficients; (2) altering use of analogies; and (3) repeatedly stressing differences between mathematical models used for chemical reactions and the actual chemistry of these reactions. Examples for undergraduate/graduate courses…

Provides an alternative derivation of the Boltzmann distribution based on the minimization of the Helmholtz free energy. (CS)